Synthesis and Performance of ZnAl@Layered Double Hydroxide Composites with Eucheuma cottonii for Adsorption and Regeneration of Congo Red Dye
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Keywords:
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Algae, Eucheuma cottonii, LDH, Congo Red, Regeneration
Abstract
This study investigates the synthesis and characterization of ZnAl-layered double hydroxide (ZnAl@LDH) composites modified with Eucheuma cottonii (EC) for the adsorption and regeneration of congo red (CR) dye. The ZnAl@LDH was synthesized using a co-precipitation method, and the composite with EC was prepared via hydrothermal techniques. The structural properties of the composites were analyzed using XRD and FTIR. Adsorption experiments were conducted to determine the effects of pH, contact time, concentration, and temperature on dye removal. The adsorption kinetics followed the pseudo-second-order (PSO) model, while the isotherm data best fitted the Freundlich model, indicating multilayer adsorption. The ZnAl@EC composite demonstrated superior adsorption capacity (243.902 mg/g at 40 °C) compared to ZnAl@LDH and EC. Thermodynamic studies revealed that the adsorption process was spontaneous and endothermic for ZnAl@LDH and EC but exothermic for ZnAl@EC. The regeneration study showed that ZnAl@EC retained significant adsorption capacity even after seven cycles, indicating its potential for practical applications in wastewater treatment.
References
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Jia, Y. H. and Z. H. Liu (2019). Preparation of Borate Anions Intercalated MgAl-LDHs Microsphere and Its Calcinated Product With Superior Adsorption Performance for Congo Red. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 575; 373–381.
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Nissa, R. C., A. H. D. Abdullah, B. Firdiana, W. Kosasih, E. S. Endah, S. Marliah, A. Rahmat, and Hidayat (2023). Characterization of Microcrystalline Cellulose From Red Seaweed Gracilaria Verucosa and Eucheuma Cottonii. IOP Conference Series: Earth and Environmental Science, 1201(1); 012101.
Noli, F., M. Sidirelli, and P. Tsamos (2024). The Impact of Phosphate Fertilizer Factory on the Chemical and Radiological Pollution of the Surrounding Marine Area (Seawater and Sediments) in Northwestern Greece. Regional Studies in Marine Science, 73.
Ravichandran, K., N. S. Jyothi, K. Thirumurugan, S. Suvathi, N. Chidhambaram, R. Uma, and B. Sundaresan (2023). Influence of Mo + F Incorporation and Point of Zero Charge on the Dye Degradation Efficacy of ZnO Thin Films. Chemical Physics, 564.
Rohmatullaili, N. Ahmad, D. Savira, D. Erviana, Zultriana, R. Mohadi, and A. Lesbani (2024). A Series of MgAl Layer Double Hydroxide-Based Materials Intercalated With Clitoria Ternatea Flower Extract as Photocatalysts in the Ciprofloxacin Degradation. Chemical Physics Impact, 8.
Sahu, A. and J. C. Poler (2024). Removal and Degradation of Dyes From Textile Industry Wastewater: Benchmarking Recent Advancements, Toxicity Assessment and Cost Analysis of Treatment Processes. Journal of Environmental Chemical Engineering, 12(5).
Shen, J., A. Shi, M. Wu, H. Zhang, and Z. Jiang (2022). Efficient Degradation of Bisphenol A Over Facilely Optimized Ternary Ag/ZnO/ZnAl-LDH Composite With Enhanced Photocatalytic Performance Under Visible Light Irradiation. Solid State Sciences, 132.
Silva, C. E. d. F., B. M. V. d. Gama, A. H. d. S. Gonçalves, J. A. Medeiros, and A. K. d. S. Abud (2020). Basic-Dye Adsorption in Albedo Residue: Effect of pH, Contact Time, Temperature, Dye Concentration, Biomass Dosage, Rotation and Ionic Strength. Journal of King Saud University - Engineering Sciences, 32(6); 351–359.
Taher, T., R. Putra, N. R. Palapa, and A. Lesbani (2021). Preparation of Magnetite-Nanoparticle-Decorated NiFe Layered Double Hydroxide and Its Adsorption Performance for Congo Red Dye Removal. Chemical Physics Letters, 777.
Tang, L., W. Chen, F. Li, J. Xu, Y. Shi, and H. Jiang (2024). The Formation and Adsorption Mechanism Studies of 3D Hydrangea-Like ZnFe-LDHs/FeOOH for the Highly Efficient Removal of Phosphate. Chemical Engineering Journal, 482.
Tye, Y. Y., A. H. Khalil, C. Y. Kok, and C. K. Saurabh (2018). Preparation and Characterization of Modified and Unmodified Carrageenan Based Films. IOP Conference Series: Materials Science and Engineering, 368(1).
Umesh, A. S., Y. M. Puttaiahgowda, and S. Thottathil (2024). Enhanced Adsorption: Reviewing the Potential of Reinforcing Polymers and Hydrogels With Nanomaterials for Methylene Blue Dye Removal. Surfaces and Interfaces, 51; 104670.
Wulandari, D., Y. Kilawati, and M. Fadjar (2018). Activity of Compounds on Seaweed Eucheuma cottonii Extract as Antioxidant Candidate to Prevent Effects of Free Radical in Water Pollution. Research Journal of Life Science, 5(3); 173–182.
Yao, C., Y. Yang, C. Li, Z. Shen, J. Li, N. Mei, C. Luo, Y. Wang, C. Zhang, and D. Wang (2024). Heavy Metal Pollution in Agricultural Soils from Surrounding Industries with Low Emissions: Assessing Contamination Levels and Sources. Science of the Total Environment, 917; 170610.
Yuliarti, O., A. D. Sentana, C. Y. Ong, Z. Abdol Rahim Yassin, L. Ng, and W. M. Koh (2023). Structural Properties of Kappaphycus alvarezii Seaweed (cottonii) Gels in the Presence of Coconut Milk. Food Hydrocolloids, 145; 109087.
Zhang, X., W. Li, X. Wang, M. Su, and Q. Lin (2024). A Novel 3D Hierarchical NiFe-LDH/Graphitic Porous Carbon Composite as Multifunctional Adsorbent for Efficient Removal of Cationic/Anionic Dyes and Heavy Metal Ions. Journal of Molecular Liquids, 411; 125753.
Zhu, S., M. A. Khan, T. Kameda, H. Xu, F. Wang, M. Xia, and T. Yoshioka (2022). New Insights into the Capture Performance and Mechanism of Hazardous Metals Cr3+ and Cd2+ onto an Effective Layered Double Hydroxide Based Material. Journal of Hazardous Materials, 426; 128062.
Zong, P., S. Wang, G. Liang, M. Shao, N. Yan, X. Xu, M. Xu, W. Li, Y. Yang, J. Chen, and Z. Qiu (2022). Eco-Friendly Approach for Effective Removal for Congo Red Dye from Wastewater Using Reusable Zn-Al Layered Double Hydroxide Anchored on Multiwalled Carbon Nanotubes Supported Sodium Dodecyl Sulfonate Composites. Journal of Molecular Liquids, 349; 118468.
Antoniak-Jurak, K., P. Kowalik, W. Próchniak, R. Bicki, and G. S?owik (2021). Heterostructural Mixed Oxides Prepared via ZnAlLa LDH or Ex-ZnAl LDH Precursors-Effect of La Content and Its Incorporation Route. Materials, 14(8); 2082.
Basit, A., A. A. Jamali, F. A. Junejo, R. Larik, S. K. Mahar, A. Sameeu, F. K. Mahar, and A. Hyder (2024). Fabrication of CuO Derived Reduced Graphene Oxide Photocatalyst for the Strategic Decolorization of Congo Red From an Aqueous Environment. Diamond and Related Materials, 142; 110839.
Cruz, E. D., J. Missau, S. R. Collinson, E. H. Tanabe, and D. A. Bertuol (2023). Efficient Removal of Congo Red Dye Using Activated Lychee Peel Biochar Supported Ca-Cr Layered Double Hydroxide. Environmental Nanotechnology, Monitoring and Management, 20; 100835.
Eid, H. A., W. S. Mohamed, A. G. Zaki, S. K. Amer, and E. H. El-Shatoury (2023). Statistical Optimization of Congo Red Biodegradation by a Bacterial Strain of Alcaligenes Faecalis. Bioresource Technology Reports, 23; 101573.
Farghali, M. A., A. M. Selim, H. F. Khater, N. Bagato, W. Alharbi, K. H. Alharbi, and I. T. Radwan (2022). Optimized Adsorption and Effective Disposal of Congo Red Dye From Wastewater: Hydrothermal Fabrication of MgAl-LDH Nanohydrotalcite-Like Materials. Arabian Journal of Chemistry, 15(11).
Firdayanti, L., R. Yanti, E. S. Rahayu, and C. Hidayat (2023). Carrageenan Extraction From Red Seaweed (Kappaphycopsis cottonii) Using the Bead Mill Method. Algal Research, 69; 102906.
Goudjil, S., S. Guergazi, T. Masmoudi, and S. Achour (2021). Effect of Reactional Parameters on the Elimination of Congo Red by the Combination of Coagulation–Flocculation With Aluminum Sulfate. Desalination and Water Treatment, 209; 429–436.
Han, J. S., S. Y. Kim, and Y. B. Seo (2022). Disk-Shaped Cellulose Fibers From Red Algae, Eucheuma cottonii, and Its Use for High Oxygen Barrier. International Journal of Biological Macromolecules, 210; 752–758.
Haryanto, B., W. B. Singh, E. S. Barus, A. Ridho, and M. R. Rawa (2017). Pseudo Order Kinetics Model to Predict the Adsorption Interaction of Corn-Stalk Adsorbent Surface With Metal Ion Adsorbate Cu (II) and Fe (II). Journal of Physics: Conference Series, 801(1); 012098.
Jabeen, A., N. S. Alsaiari, K. M. Katubi, I. Shakir, Z. A. Alrowaili, M. S. Al-Buraihi, and M. F. Warsi (2024). Synthesis and Characterisation of MXene Based-LDH Photocatalytic Materials for the Removal of Toxic Pharmaceutical Effluents. Journal of Molecular Liquids, 405.
Jia, Y. H. and Z. H. Liu (2019). Preparation of Borate Anions Intercalated MgAl-LDHs Microsphere and Its Calcinated Product With Superior Adsorption Performance for Congo Red. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 575; 373–381.
Jumaidin, R., S. M. Sapuan, M. Jawaid, M. R. Ishak, and J. Sahari (2017). Characteristics of Eucheuma cottonii Waste From East Malaysia: Physical, Thermal and Chemical Composition. European Journal of Phycology, 52(2); 200–207.
Kang, J., M. Liu, M. Qu, X. Guang, J. Chen, Y. Zhao, and B. Huang (2023). Identifying the Potential Soil Pollution Areas Derived From the Metal Mining Industry in China Using MaxEnt With Mine Reserve Scales (MaxEnt MRS). Environmental Pollution, 329; 121687.
Lesbani, A., N. Ahmad, R. Mohadi, I. Royani, S. Wibiyan, Amri, and Y. Hanifah (2024). Selective Adsorption of Cationic Dyes by Layered Double Hydroxide With Assist Algae (Spirulina Platensis) to Enrich Functional Groups. JCIS Open, 15.
Li, Z., J. Wang, D. F. Expósito, J. Zhang, C. Fu, D. Shi, and D. Y. Wang (2018). High-Performance Carrageenan Film Based on Carrageenan Intercalated Layered Double Hydroxide With Enhanced Properties: Fire Safety, Thermal Stability and Barrier Effect. Composites Communications, 9; 1–5.
Majid, N. B., I. S. B. Ibrahim, N. N. B. Sarbini, Z. A. B. Zakaria, and M. H. B. Osman (2019). The Chemical Properties of Seaweed for Modify Concrete. IOP Conference Series: Earth and Environmental Science, 220(1); 012026.
Meili, L., P. V. Lins, C. L. P. S. Zanta, J. I. Soletti, L. M. O. Ribeiro, C. B. Dornelas, T. L. Silva, and M. G. A. Vieira (2019). MgAl-LDH/Biochar Composites for Methylene Blue Removal by Adsorption. Applied Clay Science, 168; 11–20.
Nissa, R. C., A. H. D. Abdullah, B. Firdiana, W. Kosasih, E. S. Endah, S. Marliah, A. Rahmat, and Hidayat (2023). Characterization of Microcrystalline Cellulose From Red Seaweed Gracilaria Verucosa and Eucheuma Cottonii. IOP Conference Series: Earth and Environmental Science, 1201(1); 012101.
Noli, F., M. Sidirelli, and P. Tsamos (2024). The Impact of Phosphate Fertilizer Factory on the Chemical and Radiological Pollution of the Surrounding Marine Area (Seawater and Sediments) in Northwestern Greece. Regional Studies in Marine Science, 73.
Ravichandran, K., N. S. Jyothi, K. Thirumurugan, S. Suvathi, N. Chidhambaram, R. Uma, and B. Sundaresan (2023). Influence of Mo + F Incorporation and Point of Zero Charge on the Dye Degradation Efficacy of ZnO Thin Films. Chemical Physics, 564.
Rohmatullaili, N. Ahmad, D. Savira, D. Erviana, Zultriana, R. Mohadi, and A. Lesbani (2024). A Series of MgAl Layer Double Hydroxide-Based Materials Intercalated With Clitoria Ternatea Flower Extract as Photocatalysts in the Ciprofloxacin Degradation. Chemical Physics Impact, 8.
Sahu, A. and J. C. Poler (2024). Removal and Degradation of Dyes From Textile Industry Wastewater: Benchmarking Recent Advancements, Toxicity Assessment and Cost Analysis of Treatment Processes. Journal of Environmental Chemical Engineering, 12(5).
Shen, J., A. Shi, M. Wu, H. Zhang, and Z. Jiang (2022). Efficient Degradation of Bisphenol A Over Facilely Optimized Ternary Ag/ZnO/ZnAl-LDH Composite With Enhanced Photocatalytic Performance Under Visible Light Irradiation. Solid State Sciences, 132.
Silva, C. E. d. F., B. M. V. d. Gama, A. H. d. S. Gonçalves, J. A. Medeiros, and A. K. d. S. Abud (2020). Basic-Dye Adsorption in Albedo Residue: Effect of pH, Contact Time, Temperature, Dye Concentration, Biomass Dosage, Rotation and Ionic Strength. Journal of King Saud University - Engineering Sciences, 32(6); 351–359.
Taher, T., R. Putra, N. R. Palapa, and A. Lesbani (2021). Preparation of Magnetite-Nanoparticle-Decorated NiFe Layered Double Hydroxide and Its Adsorption Performance for Congo Red Dye Removal. Chemical Physics Letters, 777.
Tang, L., W. Chen, F. Li, J. Xu, Y. Shi, and H. Jiang (2024). The Formation and Adsorption Mechanism Studies of 3D Hydrangea-Like ZnFe-LDHs/FeOOH for the Highly Efficient Removal of Phosphate. Chemical Engineering Journal, 482.
Tye, Y. Y., A. H. Khalil, C. Y. Kok, and C. K. Saurabh (2018). Preparation and Characterization of Modified and Unmodified Carrageenan Based Films. IOP Conference Series: Materials Science and Engineering, 368(1).
Umesh, A. S., Y. M. Puttaiahgowda, and S. Thottathil (2024). Enhanced Adsorption: Reviewing the Potential of Reinforcing Polymers and Hydrogels With Nanomaterials for Methylene Blue Dye Removal. Surfaces and Interfaces, 51; 104670.
Wulandari, D., Y. Kilawati, and M. Fadjar (2018). Activity of Compounds on Seaweed Eucheuma cottonii Extract as Antioxidant Candidate to Prevent Effects of Free Radical in Water Pollution. Research Journal of Life Science, 5(3); 173–182.
Yao, C., Y. Yang, C. Li, Z. Shen, J. Li, N. Mei, C. Luo, Y. Wang, C. Zhang, and D. Wang (2024). Heavy Metal Pollution in Agricultural Soils from Surrounding Industries with Low Emissions: Assessing Contamination Levels and Sources. Science of the Total Environment, 917; 170610.
Yuliarti, O., A. D. Sentana, C. Y. Ong, Z. Abdol Rahim Yassin, L. Ng, and W. M. Koh (2023). Structural Properties of Kappaphycus alvarezii Seaweed (cottonii) Gels in the Presence of Coconut Milk. Food Hydrocolloids, 145; 109087.
Zhang, X., W. Li, X. Wang, M. Su, and Q. Lin (2024). A Novel 3D Hierarchical NiFe-LDH/Graphitic Porous Carbon Composite as Multifunctional Adsorbent for Efficient Removal of Cationic/Anionic Dyes and Heavy Metal Ions. Journal of Molecular Liquids, 411; 125753.
Zhu, S., M. A. Khan, T. Kameda, H. Xu, F. Wang, M. Xia, and T. Yoshioka (2022). New Insights into the Capture Performance and Mechanism of Hazardous Metals Cr3+ and Cd2+ onto an Effective Layered Double Hydroxide Based Material. Journal of Hazardous Materials, 426; 128062.
Zong, P., S. Wang, G. Liang, M. Shao, N. Yan, X. Xu, M. Xu, W. Li, Y. Yang, J. Chen, and Z. Qiu (2022). Eco-Friendly Approach for Effective Removal for Congo Red Dye from Wastewater Using Reusable Zn-Al Layered Double Hydroxide Anchored on Multiwalled Carbon Nanotubes Supported Sodium Dodecyl Sulfonate Composites. Journal of Molecular Liquids, 349; 118468.
Authors
Wibiyan, S., Royani, I., & Lesbani, A. (2024). Synthesis and Performance of ZnAl@Layered Double Hydroxide Composites with Eucheuma cottonii for Adsorption and Regeneration of Congo Red Dye. Indonesian Journal of Environmental Management and Sustainability, 8(3), 126-134. https://doi.org/10.26554/ijems.2024.8.3.126-134
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